I like to keep it simple. Acoustic version... 

(Shortened Intro, come in after trumpets) D    A    Bm    A    D    A    Bm    G (x2) 

D              A 
Jolene you're stalling again 
Bm                   G 
So I'll wait here outside in the sun 
                  D                  A 
Where you keep me waiting for a long time 
                  Bm                        G 
Soon you'll come around and let me know its time  
           D                  A 
for you and I to say goodbye Soon you'll come around 
           Bm                G                                   
and let us know its time to leave 
                     
Then you and I will  
D       A       Bm               A            D 
Say goodbye, we know that you'll never let us go 
   A      Bm               G                  D 
Jolene we know that you'll somehow make it 
   A      Bm               A            D 
Jolene we know that you'll never let us go 
   A      Bm      A      
Jolene we know. 
D             A 
Jolene you're at it again. 
Bm                   G 
So I'll wait here outside in the sun 
                   D               A 
Where you keep me waiting for a looooong time 
Bm                                 G                D 
Soon you'll come around and let me know its time to leave  
A                                   Bm               G                                  
Soon you'll come around and let me know its time to leave 
                       
Then you and I might  
D        A       Bm               A           D 
Say goodbye, we know that you'll never let us go 
  A        Bm               G                 D 
Jolene we know that you'll somehow make it 
  A        Bm               A           D 
Jolene we know that you'll never let us go 
  A        Bm                G    
Jolene we know. We'll maybe somehow make it  

(Break for AWESOME horn solo)(Mucho simplified version of guitar fill) 
(Riff?? to the horn solo) 
D    Bm    G    A  (X4) 

(No Guitar) 
Jolene we know that you'll never let us go 
                             G            D 
Jolene we know that you'll somehow make it 
   A       Bm              A            D 
Jolene we know that you'll never let us go 
   A      Bm               G              D 
Jolene we know that you'll some how meet again. 
   A           Bm       A    D 
Jolene you're stalling again 
        A            Bm       
So I'll wait here outside  
       G      D      
in the storm (Jolene we know) 

Soon you'll come around and let me know We'll maybe somehow make it 

Jolene I can see the way 

Where's the place you're gonna stop today?